Study on the preparation and spectroscopic ellipsometry of MoTe2 quantum dot films
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Affiliation:

1.Key Laboratory of Advanced Technique& Preparation for Renewable Energy Materials, Ministry of Education, School of Energy and Environment Science, Yunnan Normal University, Kunming 650500, China;2.Kunming Institute of Physics, Kunming 650223, China;3.Yunnan Key Laboratory of Advanced Photoelectric Materials & Devices, Kunming 650223, China

Clc Number:

O433.4

Fund Project:

Supported by the National Key Research and Development Program (2019YFB2203404), the Science and Technology Talents and Platform Project of Science and Technology Department of Yunnan Province (202205AC160026)

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    Abstract:

    The preparation of quantum dot thin films and the accurate measurement of optical constants are particularly important for promoting the development of quantum dot applications in the optoelectronic fields. At present, the optical constant characterization technology for MoTe2 single crystal thin films prepared by mechanical exfoliation and chemical vapor deposition methods is relatively mature. However, the optical constants of 2H-MoTe2 quantum dot films are rarely reported.In this work, 2H-MoTe2 quantum dots were prepared by ultrasonic assisted liquid phase exfoliation, and 2H-MoTe2 quantum dots with two sizes were acquired via adjusting the type of solvent and the order of ultrasonic process. The optical constants such as refractive index, extinction coefficient and dielectric constant of quantum dot films with two sizes were studied by B-spline model and Tauc-Lorentz model using spectroscopic ellipsometry. The results demonstrate that 2H-MoTe2 quantum dots with two sizes have similar refractive indices, extinction coefficients and a wider spectral absorption range from the visible to near-infrared band. And compared with MoTe2 bulk material, 2H-MoTe2 quantum dots have a lower dielectric constant.

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LI Guo-Bin, HU Kun, ZHANG Tai-Wei, YANG Ao, XIA Yi-Ping, LI Xue-Ming, TANG Li-Bin, YANG Pei-Zhi, WANG Shan-Li, CHEN Sheng-Di, YANG Li, ZHANG Yan. Study on the preparation and spectroscopic ellipsometry of MoTe2 quantum dot films[J]. Journal of Infrared and Millimeter Waves,2025,44(2):153~160

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History
  • Received:August 12,2024
  • Revised:February 18,2025
  • Adopted:October 17,2024
  • Online: February 08,2025
  • Published:
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